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|Section2= |Section3= }} A pyrylium salt is a salt containing a pyrylium cation or a derivative of it.〔 〕 The pyrylium cation is a conjugated 6-membered carbon ring system with one carbon atom replaced by a positively charged oxygen atom. It is, like benzene, an aromatic compound. A pyrylium may be any derivative of the pyrylium cation. ==Chemical properties== The carbon to oxygen double bond is also an oxonium ion, which due to aromatic stabilization is much less reactive than ordinary oxonium ions. However, the parent compound pyrylium is unstable in neutral water like oxonium salts. Pyrylium cations react with nucleophiles in the 2,4 and 6 positions and may result in ring-opening reactions. The high electronegativity of the oxygen results in the strongest single perturbation of one heteroatom in a six-membered ring. Being aromatic, pyrylium salts are easily formed from simple starting materials, and their reactivity toward nucleophiles makes them useful materials for obtaining other compounds with stronger aromatic character. Thus, pyrylium salts afford pyridines with ammonia, pyridinium salts with primary amines, pyridine-N-oxides with hydroxylamine, phosphabenzenes with phosphine derivatives, thiopyrylium salts with hydrogen sulfide, and benzene derivatives with acetonitrile or nitromethane. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Pyrylium salt」の詳細全文を読む スポンサード リンク
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